# Phase functions as solutions of integral equations

- Margarita L. Shendeleva
^{1}Email author

**13**:10

https://doi.org/10.1186/s41476-017-0038-8

© The Author(s) 2017

**Received: **22 June 2016

**Accepted: **8 March 2017

**Published: **24 March 2017

## Abstract

A phase function is an important characteristic of a scattering medium. A method to derive new analytic phase functions is proposed. The relation between a phase function and an angle-averaged single-scattering intensity, derived earlier [M. L. Shendeleva, J. Opt. Soc. Am. A **30,** 2169 (2013)], is considered as an integral equation for a phase function. This equation is classified as an Abel integral equation of the first kind, whose solution is known. Two phase functions newly derived with this method are presented.

### Keywords

Radiative transfer Phase function Successive scattering orders Integral equation Abel Single scattering Anisotropy Henyey-Greenstein## Background

The radiative transfer equation (RTE), which models light propagation in scattering media, contains two unknown functions: the radiance and the scattering phase function. Usually, the phase function is modeled separately and then inserted into the RTE. A common approach to such modelling relies on the use of Mie theory [1], which models, using the Maxwell equations, the light scattering from a single spherical particle. Mie theory was also extended to particles of other shapes [2]. In aerosols and soft tissue, various sorts of averaging over particle size distributions are applied. After averaging, the Mie phase function appears to become much smoother and can be well approximated by a co-called analytic or parametric phase function.

*g*is a parameter in the range [−1, 1] and

*μ*is the cosine of the scattering angle. The phase function is normalized such that

*g*is identically equal to the anisotropy (or asymmetry) factor

*g*

^{ ani }, defined as

Therefore, *g*
^{
ani
} = *g* for the HG phase function, where |*g*
^{
ani
}| ≤ 1.

*C*is the normalization factor,

*α*≠ 0 and

*C*=

*k*/{2

*πln*[(1 +

*k*)/(1 −

*k*)]} for

*α*= 0. Here

*α*and

*k*are real parameters, where |

*k*| ≤ 1.

*α*= 1/2 the Reynolds–McCormick function reduces to the HG phase function, and, for

*α*= 0, it reduces to the ellipsoidal phase function

*k*is a real parameter related to the anisotropy factor as

*g*

^{ ani }| ≤ 1.

More flexibility for modelling phase functions is obtained by combining two HG phase functions or a HG phase function with an isotropic phase function or with a delta function, yielding two-parameter phase functions [5] or three parameter phase functions [6].

As was pointed out by Selden [7], the main features of a phase function typically comprise a narrow forward lobe (corona), a broad diffuse background, and a narrow backscattering peak (glory). Various analytic phase functions that model these three major components were proposed by Cornette and Shanks [8], Liu [9], Draine [10] and many others (see the review of Sharma [11]). It should be noted that the influence of the choice of the analytic phase function in photon transport introduces errors in the determination of optical parameters that are difficult to evaluate [12].

*P*

_{ n }(

*μ*),

*N*is finite. The radiance is also extended to a series of Legendre polynomials and, from the RTE, one eventually obtains a system of equations for unknown coefficients

*b*

_{ n }.

In this paper, we apply an inverse procedure of a different kind. First, we expand the radiance in successive scattering orders and then exploit the relation between the first-order angle-averaged scattering intensity and the phase function. The first part of this problem was solved, using the successive order expansion developed by Paasschens [16], in Shendeleva [17]. Here we focus on the second part. Consider first a few examples illustrating the relation between the first-order scattering intensity and the phase function.

*r*is the distance from the point source,

*t*is the time from the moment of photon emission,

*v*is the speed of light in the medium,

*l*

_{ s }is the scattering length, and H (x) is the Heaviside step function that equals zero for

*x*< 0 and one for

*x*≥ 0.

*g*| ≤ 1/3, the angle-averaged single-scattering intensity has been found as [17, 18]

*u*=

*r*/(

*vt*).

Generally, there is a one-to-one correspondence between a phase function and a first-order scattering intensity. For a given phase function, the first-order angle-averaged intensity (also called a single-scattering intensity) can be found from Eq. (21) of Shendeleva [17]. In this paper, we consider an inverse problem: Given the fist-order angle-averaged intensity, find the corresponding phase function. The integral equation for this purpose is derived in the next section. Fortunately, this equation happens to be an integral equation of the Abel type, whose solutions are known [19]. Sections 3 and 4 provide examples of the application of this equation.

## Derivation of the integral equation

*p*(

*s*⋅

*ŝ*') is a phase function, normalized such that ∫

_{4π }

*p*(

*ŝ*⋅

*ŝ*')

*dŝ*= 1, where

*ŝ*' and

*ŝ*are directions before and after a scattering event, respectively, and

*μ*

_{ s }and

*μ*

_{ a }are the scattering and absorption coefficients, respectively, related to the scattering length

*l*

_{ s }= 1/

*μ*

_{ s }and to the absorption length

*l*

_{ a }= 1/

*μ*

_{ a }. An instantaneous point source is represented by delta functions,

where *ℏω* is photon’s energy, and *N*
_{0} is the number of photons emitted at *t* = 0. Note that, in the following, we consider a non-absorbing case, since absorption enters into the solution through the exponential factor *Exp*(−*μ*
_{
a
}
*vt*) (16).

*N*= 0 describes the unscattered radiance, the term with

*N*= 1corresponds to the radiance scattered once, and so forth. Correspondingly, for the angle-averaged intensity, which is defined as

*μ*is the cosine of the scattering angle

*θ*and

*ξ*is the cosine of the angle

*α*between the direction from the source to the observation point and the direction from the scattering point to the observation point (as shown in Fig. 1 of Shendeleva [17]). Using the notation

*r*= 2

*c*,

*vt*= 2

*a*, and

*c*/

*a*=

*r*/(

*vt*) =

*u*, we can express cosines

*μ*and

*ξ*as

*x*is a coordinate along the

*x*-axis in the range [−

*a*,

*a*].

*ξ*to

*μ*, we transform Eq. (18) to

*χ*= 2

*u*

^{2}− 1, where

*χ*varies in the range [−1, 1].

*F*' (

*τ*) means the derivative with respect to the argument. Note also the normalization conditions in Eq. (23). From the normalization of the phase function given by Eq. (2), one obtains the normalization for

*F*(

*χ*),

## Examples of solutions

### Ellipsoidal phase function

where *χ* = 2*r*
^{2}/(*vt*)^{2} − 1 .

*k*. The superscript

*Da*indicates that expression (1 +

*k*

^{2}− 2

*kχ*) in the denominator enters in degree

*a*. Consider the following two particular cases.

### Phase function D1

*a*= 1 and the right-hand side of Eq. (22) takes the form

*p*

^{ D1}is found to be

It should be noted that *p*
^{
D1}(*μ*) takes on negative values for *k* < − 0.8; therefore, the range of parameter *k* should be restricted to − 0.8 < *k* < 1.

*k*is shown in Fig. 1. Note that, for − 0.2 <

*k*< 1, the anisotropy factor closely follows the linear dependence

*g*

^{ ani }=

*k*, which is characteristic of the HG phase function. In contrast to the HG phase function, the phase function D1 has a simple analytic form for the single-scattering angle-averaged intensity. It is shown in the Appendix that this fact can be used to approximate the single-scattering intensity for the HG phase function by the single-scattering intensity for the D1 phase function. A plot for the phase function

*p*

^{ D1}(

*μ*) versus the scattering angle

*θ*is shown in Fig. 2.

### Phase function D4

The notation D4 means that expression (1 + *k*
^{2} − 2*kχ*) enters the denominator in degree 4.

*Q*is the normalizing factor, which can be analytically calculated as follows. Changing back to the variable

*u*

^{2}= (

*χ*+ 1)/2 in Eq. (34), one can write the normalization condition as

*F*

^{ D4}(

*χ*) can be written in the form

where *Q* is given by Eq. (36).

*g*

^{ ani }versus parameter

*k*. It can be seen that the curve

*g*

^{ ani }(

*k*) is closely approximated by the curve

*k*≤ 1. A polar plot for the phase function

*p*

^{ D4}(

*μ*), and also for

*p*

^{ D1}(

*μ*), is shown in Fig. 4. It should be noted that, for polar plots, it is convenient to make the change of variable

*τ*+ 1 = (1 +

*μ*)(1 −

*y*

^{2}), which transforms the integral in Eq. (39) to the integral with constant limits

The use of the phase function D4 will be shown elsewhere.

## Conclusion

We have derived an integral equation that relates a phase function and an angle-averaged intensity for the first-order scattering, Eq. (21). The solution of this equation, classified as an Abel integral equation of the first kind, can be readily written down as given by Eq. (23). Then, we consider several examples of application of this equation. The first example is merely illustrative, since it concerns the ellipsoidal phase function for which the first-order intensity is known. This example is useful in the sense that it gives an idea of what the first-order intensity can look like. In the two subsequent examples, small modifications of the fist-order intensity allow us to derive two new one-parameter phase functions. The first one, denoted by D1, has the useful property that its anisotropy factor is practically identical to the parameter of the phase function (in the range − 0.2 < *k* < 1). The same property is characteristic of the HG phase function. Although the function D1 is more complicated than the HG phase function, it has a very simple first-order scattering intensity. The second phase function, D4, has a simple algebraic relation (in the range 0 < *k* < 1) between the anisotropy factor and the parameter of the phase function, as given by Eq. (40). These examples show that, through small modifications of the single-scattering intensity, one can derive new phase functions with useful properties.

## Declarations

### Competing interests

The author declares that she has no competing interests.

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## Authors’ Affiliations

## References

- Mie, G.: Contributions to the optics of turbid media, particularly of colloidal metal solutions. [in German]. Annal. Phys.
**25**(N3), 377–445 (1908)ADSView ArticleGoogle Scholar - Bohren, C.F., Huffman, D.R.: Absorption and Scattering of Light by Small Particles. Wiley, New- York (1983)Google Scholar
- Henyey, L.G., Greenstein, J.L.: Diffuse radiation in the galaxy. Astrophys. J.
**93**, 70–83 (1941)ADSView ArticleMATHGoogle Scholar - Reynolds, L.O., McCormick, N.J.: Approximate two-parameter phase function for light scattering. J. Opt. Soc. Am.
**70**, 1206–1212 (1980)ADSView ArticleGoogle Scholar - Irvin, W.M.: Multiple scattering by large particles. Astrophys. J.
**142**, 1563–1575 (1965)ADSView ArticleGoogle Scholar - Kattawar, G.W.: A three-parameter analytic phase function for multiple scattering calculations. J. Quant. Spectrosc. Radiat. Transf.
**15**, 839–849 (1975)ADSView ArticleGoogle Scholar - Selden, A.C.: Attenuation and impulse response for multiple scattering of light in atmospheric clouds and aerosols. Appl. Opt.
**45**, 3144–3151 (2006)ADSView ArticleGoogle Scholar - Cornette, W.M., Shanks, J.G.: Physically reasonable analytic expression for the single-scattering phase function. Appl. Opt.
**31**, 3152–3160 (1992)ADSView ArticleGoogle Scholar - Liu, P.: A new phase function approximating to Mie scattering for radiative transport equations. Phys. Med. Biol.
**39**, 1025–1036 (1994)View ArticleGoogle Scholar - Draine, B.T.: Scattering by interstellar dust grains. I. Opt. Ultraviolet Astrophys. J
**598**, 1017–1025 (1992)View ArticleGoogle Scholar - Sharma, S.K.: A review of approximate analytic light-scattering phase functions. In: Kokhanovsky, A.A. (ed.) Light Scattering Reviews, vol. 9, pp. 53–100. Springer, Berlin (2015)Google Scholar
- Selden, A.C.: Photon transport parameters of diffuse media with highly anisotropic scattering. Phys. Med. Biol.
**49**, 3017–3027 (2004)View ArticleGoogle Scholar - Zaneveld, J.R.V., Pak, H.: Some aspects of the axially symmetric submarine daylight field. J. Geophys. Res.
**77**, 2677–2680 (1972)ADSView ArticleGoogle Scholar - Case, K.M.: Inverse problem in transport theory. Phys. Fluids
**16**, 1607–1611 (1973)ADSMathSciNetView ArticleGoogle Scholar - McCormick, N.J.: Ocean optics phase-function inverse equations. Appl. Opt.
**31**, 4958–4961 (2002)ADSView ArticleGoogle Scholar - Paasschens, J.C.J.: Solution of time-dependent Boltzmann equation. Phys. Rev. E
**56**, 1135–1141 (1997)ADSView ArticleGoogle Scholar - Shendeleva, M.L.: Single-scattering solutions to radiative transfer in infinite turbid media. J. Opt. Soc. Am. A
**30**, 2169–2174 (2013)ADSView ArticleGoogle Scholar - Fomenko, V.N., Shvarts, F.M., Shvarts, M.A.: Exact description of photon migration in anisotropically scattering media. Phys. Rev. E
**61**, 1990–1995 (2000)ADSView ArticleGoogle Scholar - Bitsadze, A.V.: Integral Equations of First Kind. World Scientific, Singapore (1995)View ArticleMATHGoogle Scholar
- Reilly, D.M., Warde, C.: Temporal characteristics of single-scatter radiation. J. Opt. Soc. Am.
**69**, 464–470 (1979)ADSView ArticleGoogle Scholar